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RPP Plating (PRP, Reverse Pulse Plating)
Electrodeposition using a DC rectifier supplying current for a predetermined amount of time, and then reversing that current for a shorter time period, to lay down a finer grain structure, and reduce the porosity of the deposit.

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Electroplating - My pH is dropping...
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March 29, 2004

Description: pH is normally within the range 3.8 to 4.2, 4.0 being optimal for most stamperforming applications. In a normally functioning bath, the pH rises gradually and the galvanics technician/operator adds small amounts of sulfamic acid to compensate.

If, during the course of a plating cycle, the pH starts to go down (assuming no sulfamic acid has been just added), then this is the inducation of a problem with the chemistry of the bath.

Causes

  • Anodes have become passive







  • High pH for long periods (24 hours or more)







  • Low boric acid level (<30g/l)

  • Low flow




Solution

  • Remove and clean anodes. First rinse thoroughly with DI water, and then soak in 25-30 g/l sulfamic acid solution for a minimum of 4 hours. Then rinse thoroughly with DI water and replace in cell. Dummy plate in the cell at 2.0 volts for 3-4 hours. This should activate the anodes
  • Check pH frequently (daily or several times per day). Maintain the pH within the specified range by using sulfamic acid when the pH rises to 4.1-4.2. Make sure pH meters/probes are calibrate. Never reuse calibration buffer for more than 8 hours. Keep a spare pH probe on hand.
  • Make additions of boric acid using the "boric bag" or "boric sock".
  • Check filters and verify good flow in the cells by observing the turbulence and overflow in the cell.

Effects: Compressive stress which will lead to problems in the molding process. Continued operation at low pH can cause permanent damage to the electroforming bath.
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